![]() DEFORMABLE HULL DEVICE COMPRISING A PIEZOELECTRIC INTERNAL CIRCUIT
专利摘要:
A device (10) comprises a deformable shell (12) delimiting an internal volume (14), and: - an elastic band (18, 30, 32) suspended in the internal volume (14) and comprising two ends integral with the deformable shell (12), said strip (18, 30, 32) comprising a piezoelectric material (30, 32) so as to produce an electric voltage under the effect of the deformation of the shell (12) and two electrodes for collecting the voltage; and an electronic circuit (34) for processing the voltage, arranged on the elastic band (18, 30, 32) and connected to the electrodes of the elastic band (18, 30, 32). 公开号:FR3016300A1 申请号:FR1450299 申请日:2014-01-15 公开日:2015-07-17 发明作者:Guillaume Savelli;Philippe Coronel;Thomas Huguet 申请人:Commissariat a lEnergie Atomique CEA;Commissariat a lEnergie Atomique et aux Energies Alternatives CEA; IPC主号:
专利说明:
[0001] FIELD OF THE INVENTION The invention relates to the field of the functionalization of balls and balloons, in particular deformable balls and balloons, in particular in the field of sport and / or physical rehabilitation. DEFORMABLE HULL DEVICE COMPRISING A PIEZOELECTRIC INTERNAL CIRCUIT and / or leisure, such as tennis balls. [0002] STATE OF THE ART In ball and ball sports and physical rehabilitation based on such objects, it is useful to have statistics that allow players to analyze their game and medical staff to evaluate the quality of exercises performed. by the patients. [0003] Usually, these statistics are collected manually by counting for example the number of strikes, rebounds or other than a player or a patient exerts on a ball for a predetermined duration. There is thus an interest in incorporating into electronic balls and balloons electronic functions for automatically performing statistics and / or converting and storing the mechanical energy provided to these objects when they are used in electrical energy. Document US 2011/136603 discloses a sports ball comprising a deformable shell delimiting an internal volume under pressure, such as for example a tennis ball, and comprising a piezoelectric element disposed on or in the deformable shell to convert the corresponding mechanical energy. the deformation of the hull into electrical energy, and an electronic circuit comprising a battery for storing the electrical energy thus produced and a processing circuit powered by the battery, such as for example an accelerometer, a pressure sensor or a GPS system . This document, however, is silent on how to integrate these different components in the ball. However, this integration generally targets several objectives that can be contradictory. [0004] First, it is sought a conversion rate of mechanical energy into high electrical energy because the electrical energy can be used to power electronic circuits requiring a high level of energy to operate. [0005] Then, the components integrated in the ball must interfere at least its aerodynamics and deformations, because it is sought a functionalized ball whose mechanical characteristics are close, ideally identical to those of a conventional ball to be used in place and place thereof, especially in the field of sports in which the balls and balloons must meet very strict criteria to be considered compliant. Finally, it is preferable that the components are mechanically robust to cope with mechanical stresses that can be high due to the shocks and significant accelerations experienced by the bullet. The inventors have also noted, in the context of tests on various types of electronic circuit and electrical connections integrated in a tennis ball, frequent breakages of these components. SUMMARY OF THE INVENTION The object of the present invention is to propose a deformable shell device delimiting an internal space which comprises circuits producing electricity under the effect of deformation of the hull and exploiting said electricity production at the same time. processing and / or storage purposes, which has a mechanical behavior similar to that of a device without such circuits, and whose circuits are robust while having a high rate of conversion of mechanical energy into electrical energy. For this purpose, the subject of the invention is a device comprising a deformable shell delimiting an internal volume, the device comprising: an elastic band suspended in the internal volume and comprising two ends integral with the deformable shell, said strip comprising a piezoelectric material so as to produce an electric voltage under the effect of the deformation of the shell and two electrodes for collecting the voltage; and an electronic circuit for processing the voltage, connected to the electrodes of the elastic band. By "deformable" is meant here a shell adapted to deform under the effect of impacts suffered by it during a standard use of the hull. [0006] In other words, the device according to the invention offers a special compromise between the various objectives described above. [0007] First, the elastic band deforms regardless of the location of an impact on the bullet or the direction of the acceleration thereof, which allows a minimum conversion rate of mechanical energy in electrical energy. [0008] In addition, since a band is by definition an object having a limited width compared to its length, the band has a limited contact zone with the deformable shell, which makes it possible to limit the effects of the band on the deformation properties of the shell. . [0009] Finally, since the electronic circuit is disposed directly on the elastic band, it is therefore not subjected directly to impacts through the shell and there is no need for long electrical connections, usually fragile, as it could the case of an electronic circuit arranged at a distance from the piezoelectric material. In addition, if the elastic band is placed on a plane of symmetry of the shell, the electronic circuit then minimizes the behavior of the device. According to one embodiment, the elastic band comprises an elastic support layer having two opposite faces, and a layer made of piezoelectric material disposed on at least one of said faces. In this way, the elasticity function, which transfers the mechanical energy undergone by the shell to the piezoelectric material, and the piezoelectric function are largely decoupled, which makes it possible to optimize each of them. [0010] According to one embodiment, the elasticity coefficient of the support layer is substantially identical to the elasticity coefficient of the deformable shell. An important coefficient of elasticity, or "Young modulus", and a Shore coefficient allow a significant deformation of the elastic band, and consequently a significant deformation of the piezoelectric material, and corollary, a significant production of electricity. However, it has been observed a phase shift between the deformation of the deformable shell and the deformation of the elastic band all the more important that their elasticity coefficients are different from each other. This phase shift can significantly impact the behavior of the hull, especially during rebound. For example. By minimizing the difference in elasticity coefficients, this phase shift is minimized. [0011] According to one embodiment, the shore coefficient D on the scale D of the support layer is greater than or equal to 70 and the thickness of the support layer is greater than or equal to 3 millimeters. As a variant, the Shore coefficient on the D scale of the support layer is greater than or equal to 70 and the ratio between the length of the support layer and the thickness of the latter is less than 2200. In short, these ranges of values make it possible to minimize the effect of the aforesaid phase shift on the behavior of the shell while ensuring a large deformation of the elastic band, and therefore a large production of electricity. [0012] More particularly, the support layer is made of polyurethane or ethylene-propylene-diene monomer ("EDPM"), these materials having in fact an appropriate Shore coefficient to limit the phenomenon of phase shift. According to one embodiment, the layer of piezoelectric material is made of piezoelectric polymer, especially polyvinylidene fluoride ("PVDF"), and is covered with a layer of plastic. PVDF has the advantage of being light, flexible and mechanically resistant. In addition, it has been found that covering the piezoelectric layer with a plastic film makes it possible to reinforce the mechanical robustness of the latter, and thus to make it less sensitive to breaks that may occur as a result of violent shocks on the deformable shell. According to one embodiment, the deformable shell and the elastic band each comprise a plane of symmetry, and the planes of symmetry of the deformable shell and the elastic band coincide, thereby reducing the effect of the position of a impact suffered by the deformable shell on the deformation of the elastic band, and thus on the production of electrical energy by the piezoelectric material. According to one embodiment, the deformable shell is a sphere, and the elastic band is a rectangular parallelepiped of width less than 50% of the diameter of the sphere. [0013] The ends of the elastic band are in particular housed in the shell by gluing. However, it is found that a large volume of glue to maintain the band integral with the hull impacts the mechanical properties of the hull. It has also been found that by choosing a width less than 50% of the diameter of the shell, this impact is substantially reduced while allowing sufficient bonding. According to one embodiment, the deformable shell is a sphere and the center of gravity. the assembly formed of the elastic band and the electronic circuit is arranged in the center of the sphere. The centroid of the device is thus the same as that of the shell, which minimizes the impact of the presence of the band and the electronic circuit on the mechanical properties of the device. According to one embodiment, the electronic circuit comprises an energy storage element. The stored energy thus makes it possible to operate circuits requiring a large electrical power, such as, for example, radiofrequency transmission modules making it possible to communicate with the outside of the shell. More particularly, the storage element comprises a micro-battery formed on a flexible or rigid substrate. This type of electrical energy storage means is very light, usually of a low weight and a small area for a large storage capacity. More particularly, the electronic circuit comprises a circuit for producing data from the electrical voltage produced by the elastic band, and a wireless transmission circuit of said data outside the deformable shell, said production and transmission circuits. being powered by the electrical energy storage element. According to one embodiment, the electronic circuit comprises a circuit for determining the force exerted on the deformable shell as a function of the amplitude of the tension produced by the elastic band. It has indeed been found that there is a bijectivity relation between the amplitude of the electrical voltage produced and the amplitude of the force exerted on the deformable shell. It is therefore possible to deduce the latter from the voltage produced, for example by using an abacus. [0014] BRIEF DESCRIPTION OF THE FIGURES The invention will be better understood on reading the following description, given solely by way of example, and made with reference to the accompanying drawings, in which: FIG. 1 is a diagrammatic sectional view of FIG. a tennis ball having an upper face of an energy recovery system according to the invention; Figure 2 is a schematic sectional view along the plane II-II of Figure 1; Figure 3 is a schematic sectional view illustrating the flexion of an elastic band forming part of the energy recovery system of Figures 1 and 2 in two impact positions on the tennis ball; Figure 4 is a plot illustrating the voltages produced by two piezoelectric membranes disposed on either side of the elastic band during an impact on the tennis ball; Figure 5 is a schematic sectional view of the tennis ball illustrating the phase shift between the movement of the tennis ball and the movement of the elastic band; and FIG. 6 is a diagrammatic sectional view of a piezoelectric membrane forming part of the constitution of the energy recovery system. DETAILED DESCRIPTION OF THE INVENTION It will now be described, with reference to FIGS. 1 and 2, a tennis ball 10 according to the invention. The tennis ball 10 comprises a deformable spherical shell 12 defining a hollow internal volume 14. The shell 12 consists for example of a rubber layer covered with an outer layer of felt and the internal volume 14 comprises air under a pressure greater than atmospheric pressure, in particular a pressure of the order of 2 bars. The tennis ball 10 has a diameter of between 6.5 cm and 6.9 cm, and a mass of between 56 grams and 59 grams. The tennis ball 10 comprises in the volume 14, an energy conversion and information processing system 16 comprising: a support band 18, made of an elastic material, for example polyurethane, of the EDPM, rubber or neoprene. The strip 18 has for example the shape of a rectangular parallelepiped, whose two ends 20, 22 are integral with the shell 12, for example by being housed and glued in respective notches of the shell 12, and comprising two opposite faces 24 , 26; a piezoelectric membrane, 30 and 32 disposed on one or each of the faces 24, 26 of the strip 18, secured to said face, for example by gluing, and comprising two electrodes (not shown) for collecting the voltage produced by the membrane under the effect of the deformation thereof; and an electronic circuit 34, disposed on one and / or the other of the faces 24, 26 of the strip 18, and secured to the strip, for example by gluing, the circuit 34 being electrically connected to the electrodes of the piezoelectric membranes 30 and 32. [0015] In operation, as illustrated in FIG. 3, when the tennis ball 10 undergoes an impact or an acceleration, for example a rebound on the ground, the shell 12 is deformed, which causes the deformation of the elastic band 18, in particular its bending. The piezoelectric membranes 30 and 32 are thus also deformed and thus produce an electrical voltage across their respective electrodes. FIG. 4 is a plot of the voltages V1 and V2 produced respectively by the piezoelectric membranes 30 and 32 following a strike on the tennis ball 10, the tensions being of opposite signs due to the work in compression of one of the membranes during that the other membrane works in tension. The amplitude of the first peak of the voltage is directly related to the force exerted on the bale 10, the following oscillations corresponding to the oscillation of the band 18 until it returns to its rest position, voltages of an amplitude several hundred volts obtainable by the invention, as will be described in more detail later. [0016] The system 16 is advantageously optimized so that the bullet according to the invention has a mechanical behavior, especially in terms of deformation and aerodynamics, close to the behavior of a conventional tennis ball without such a system. [0017] Firstly, at rest, the mass barycenter of the system 16 coincides with the center 40 of the ball 10. The system 16 also has at least one plane of symmetry 36, 38, coinciding with a plane of symmetry of the tennis ball 10 passing through the center 40 of it. The system 16 thus has a symmetrical weight distribution adapted to the spherical geometry of the bale 10. [0018] Advantageously, the elasticity coefficient of the elastic band 18 is chosen so as to minimize the phase difference between the deformation of the shell 12 and the deformation of the strip 16. As illustrated in FIG. 5, when the ball 10 begins to take off at the instant "t" of the surface on which it has been impacted, for example the ground in the case of a rebound, as illustrated by the arrow 42, the elastic band 18 is still moving in an opposite direction , as illustrated by the arrow 44, the movement of the strip 18 and the ball 10 having the same direction after a duration At, as illustrated by the arrows 46, 48. Such a phase shift can significantly impact the rebound of the ball. Choosing a coefficient of elasticity and hardness of the elastic band 18 close to the elastic coefficient of the shell 12 makes it possible to significantly reduce this phase shift, and thus to obtain a behavior similar to a conventional tennis ball. [0019] The amplitude of the phase shift also depends on the total weight of the system 16, so that the elasticity coefficient of the band 18 is determined according to this weight. More particularly, it has been observed that a strip consisting of a D-scale shore coefficient material greater than 70 and having a thickness greater than 3 mm makes it possible to obtain a rebound close to that of a bullet without the system 16. The same effect has been observed for a shore coefficient D on the scale D of the support layer 18 is greater than or equal to 70 and the ratio between the length of the support layer 18 and the thickness of this c is less than 2200. For example, a strip 18 consisting of polyurethane, shore coefficient equal to 80, or EDPM, shore coefficient equal to 70, a width of 15 mm and a thickness of 4 mm allows a rebound greater than or equal to 80% of the rebound of a ball. Preferably, the width of the band 18 is less than 50% of the diameter of the shell 12 so as to minimize the volume of band in the shell and the volume of glue used to fix the band 18 in the shell 12, and consequently reduce the impact of the presence of the band on the deformation properties of the shell 12. Referring to FIG. 6, the piezoelectric membranes 30, 32 each comprise: a piezoelectric film 50, of a thickness advantageously between 10 micrometers and 200 micrometers, made in one piece or in several pieces; two metal layers 52, 54, of a thickness of a few nanometers to several tens of micrometers each, deposited on either side of the piezoelectric film 50, consisting for example of silver, copper nitride, aluminum, and forming two electrodes for collecting electric charges produced by the film 50; optionally two layers of flexible reinforcements 56, 58, for example of plastic, such as polyethylene terephthalate ("PET") or polyethylene naphthalate ("PEN") deposited respectively on the electrodes 52, 54. Advantageously, the piezoelectric film 50 is composed of polyvinylidene fluoride ("PVDF") which has the advantage of being light, flexible and mechanically resistant. Alternatively, the film 50 is made of titanium lead zirconate ("PZT"), zinc oxide ("ZnO"), or a composite material of at least two of these materials and PVDF. . For example, the piezoelectric membranes are "DT sensors" manufactured by the company Measurement Specialties, Inc. 35 The electronic circuit 34 implements functions of analysis and treatment of the voltages delivered by the piezoelectric membranes 30, 32 and includes a electrical energy storage element and a data production circuit. The circuit 34 is designed in particular to disturb the aerodynamic behavior of the ball 10 to a minimum. First of all, the electronic circuit 34 is chosen to be as light as possible in view of the functions it implements. In particular, the electrical energy storage element advantageously consists of a micro-battery formed on a flexible or rigid substrate. For example, the storage element is a rigid substrate micro-battery of the "EnerChip" range of Cymbet® Corp., for example a reference micro-battery "CBC050-M8C" with an area of 8x8 mm2 for a capacity of 50 i.tAh, or a micro-battery with a flexible substrate from Solicore®, Inc., for example a reference micro-battery "SF-2529-10EC" with a foldable surface of 25, 75x29 mm2 for a capacity of 10 mAh. Alternatively, the electrical energy storage element comprises one or more capacities and / or one or more super-capacitors. The data production circuit is for example a printed circuit comprising an electronic chip equipped with a microcontroller for processing data and a radiofrequency transmission module, for example according to the ZigBee protocol. The data production circuit is electrically powered by the electrical energy storage element and / or an integrated battery, of the "button" battery type. [0020] For example, the data production circuit performs a function of processing electrical pulses produced by the piezoelectric membranes 30, 32 and producing data relating to said pulses. Thus, the electronic circuit 34 may comprise: a circuit for counting the number of pulses produced since the putting into service of the tennis ball, a circuit for determining the average or individual intensity of the pulses, and / or a circuit for determining the average or individual duration of the pulses, - a radio-frequency transmitter making it possible to locate the ball on a tennis court, which makes it possible, for example, to know whether a ball is good or faulty, - an accelerometer enabling determine the speed of the ball. [0021] The data thus produced are for example stored in an internal memory of the circuit 34 and / or transmitted by the wireless communication outside the ball for their collection. [0022] In particular, knowing the number of pulses makes it possible to know, in addition to the number of impacts suffered by the bullet, the state of wear thereof, since this state of wear depends in particular directly on this number. The number of impacts, their intensity and their duration also constitute useful statistical data for a player who can thus know the strength of his strikes and the type of strikes he applies to the ball, etc. [0023] In particular, it has been observed that there is a bijective link between the amplitude of the first pulse following an impact on the bullet and the force of this impact. The data production circuit comprises, for example, an abacus memorizing force values as a function of voltage amplitude and calculates the force exerted on the bale as a function of the amplitudes of memorized voltages. [0024] Advantageously, the circuit 34 is distributed between two parts, arranged on either side of the elastic band 18 in order to distribute its weight and to obtain that the barycentre of the system 16 is disposed in the center of the bale and on a plane of symmetry of the system 16, which reduces the dependence of electricity production at the position of an impact on the hull 12 or with respect to the direction of an acceleration suffered by the ball 10. For example, the elements electrical energy storage are disposed on one side of the elastic band 18, and the data generating circuit is disposed on the other side of the band 18. [0025] It has been described a tennis ball. Obviously, the invention applies to all types of balls and ball, and generally to any deformable shell object. It has been described applications to the sport. Obviously, the invention applies to other types of activity, including physical rehabilitation activities using bullets, balloons, or other statistics produced by such objects according to the invention allowing medical personnel to study, for example, the quality of the exercises followed by the patients.
权利要求:
Claims (5) [0001] REVENDICATIONS1. Device (10) comprising a deformable shell (12) delimiting an internal volume (14), the device comprising: - an elastic band (18, 30, 32) suspended in the internal volume (14) and comprising two ends integral with the shell deformable (12), said band (18, 30, 32) comprising a piezoelectric material (30, 32) so as to produce an electric voltage under the effect of the deformation of the shell (12) and two electrodes for collecting the voltage ; and an electronic circuit (34) for processing the voltage, arranged on the elastic band (18, 30, 32) and connected to the electrodes of the elastic band (18, 30, 32). A device according to claim 1, wherein the elastic band (18) comprises an elastic support layer (18) having two opposite faces, and a layer (30, 32) made of piezoelectric material disposed on at least one of said faces. Device according to claim 2, wherein the elasticity coefficient of the support layer (18) is substantially identical to the elasticity coefficient of the deformable shell (12). Device according to claim 2 or 3, wherein the shore coefficient of the support layer (18) is greater than or equal to 70 and the ratio between the length of the support layer (18) and the thickness thereof is less than 2200. The device of claim 2, 3 or 4, wherein the support layer (18) is made of polyurethane or ethylene-propylene-diene monomer. Device according to claim 2, 3, 4 or 5, wherein the layer of piezoelectric material (30, 32) consists of piezoelectric polymer (50), especially polyvinylidene fluoride, and is covered with a layer of plastic (56). , 58). Device according to any one of the preceding claims, in which the deformable shell (12) and the elastic band (18, 30, 32) each comprise a plane of symmetry, and in which the planes of symmetry of the deformable shell and the elastic band coincide. 10 [0002] 2. 15 [0003] 3. 20 [0004] 4. 25 [0005] 5. 306. 7. 358. Device according to any one of the preceding claims, wherein the deformable shell (12) is a sphere, and wherein the elastic band (18, 30, 32) is a rectangular parallelepiped of lower width at 50% of the diameter of the sphere. 9. Device according to any one of the preceding claims, wherein the deformable shell (12) is a sphere and wherein the barycentre of the assembly formed of the elastic band (18, 30, 32) and the electronic circuit (34). ) is arranged in the center of the sphere. 10. Device according to any one of the preceding claims, wherein the electronic circuit (34) comprises an electrical energy storage element. Apparatus according to claim 10, wherein the electrical energy storage element comprises a micro-battery formed on a flexible or rigid substrate. Apparatus according to claim 10 or 11, wherein the electronic circuit (34) comprises a data generating circuit from the electrical voltage produced by the elastic band, and a wireless transmission circuit of said data to the outside the deformable shell, said production and transmission circuits being powered by the electrical energy storage element. 13. Device according to any one of the preceding claims, wherein the electronic circuit (34) comprises a force determining circuit exerted 25 on the deformable shell as a function of the amplitude of the tension produced by the elastic band. 14. Device according to any one of the preceding claims, wherein the deformable shell (12) is a tennis ball. 30 10
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2015-02-02| PLFP| Fee payment|Year of fee payment: 2 | 2016-02-01| PLFP| Fee payment|Year of fee payment: 3 | 2017-01-31| PLFP| Fee payment|Year of fee payment: 4 | 2018-01-31| PLFP| Fee payment|Year of fee payment: 5 | 2020-01-30| PLFP| Fee payment|Year of fee payment: 7 | 2021-10-08| ST| Notification of lapse|Effective date: 20210905 |
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申请号 | 申请日 | 专利标题 FR1450299A|FR3016300B1|2014-01-15|2014-01-15|DEFORMABLE HULL DEVICE COMPRISING A PIEZOELECTRIC INTERNAL CIRCUIT|FR1450299A| FR3016300B1|2014-01-15|2014-01-15|DEFORMABLE HULL DEVICE COMPRISING A PIEZOELECTRIC INTERNAL CIRCUIT| PCT/FR2014/053307| WO2015107277A1|2014-01-15|2014-12-12|Device with deformable shell including an internal piezoelectric circuit| EP14827826.0A| EP3094386B1|2014-01-15|2014-12-12|Device with deformable shell including an internal piezoelectric circuit| US15/176,387| US10350461B2|2014-01-15|2016-06-08|Device with deformable shell including an internal piezoelectric circuit| 相关专利
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Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
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